Relative dating Studies of strata , the layering of rocks and earth, gave naturalists an appreciation that Earth may have been through many changes during its existence. These layers often contained fossilized remains of unknown creatures, leading some to interpret a progression of organisms from layer to layer. Lomonosov's ideas were mostly speculative. In the Comte du Buffon tried to obtain a value for the age of Earth using an experiment: He created a small globe that resembled Earth in composition and then measured its rate of cooling.
This led him to estimate that Earth was about 75, years old. Other naturalists used these hypotheses to construct a history of Earth , though their timelines were inexact as they did not know how long it took to lay down stratigraphic layers. This was a challenge to the traditional view, which saw the history of Earth as static,[ citation needed ] with changes brought about by intermittent catastrophes.
Many naturalists were influenced by Lyell to become "uniformitarians" who believed that changes were constant and uniform. His calculations did not account for heat produced via radioactive decay a process then unknown to science or, more significantly, convection inside the Earth, which allows more heat to escape from the interior to warm rocks near the surface. For biologists, even million years seemed much too short to be plausible. In Darwin's theory of evolution , the process of random heritable variation with cumulative selection requires great durations of time.
According to modern biology, the total evolutionary history from the beginning of life to today has taken place since 3. Huxley , attacked Thomson's calculations, suggesting they appeared precise in themselves but were based on faulty assumptions. The physicist Hermann von Helmholtz in and astronomer Simon Newcomb in contributed their own calculations of 22 and 18 million years respectively to the debate: However, they assumed that the Sun was only glowing from the heat of its gravitational contraction.
The process of solar nuclear fusion was not yet known to science. In John Perry challenged Kelvin's figure on the basis of his assumptions on conductivity, and Oliver Heaviside entered the dialogue, considering it "a vehicle to display the ability of his operator method to solve problems of astonishing complexity. Charles Darwin 's son, the astronomer George H. Darwin , proposed that Earth and Moon had broken apart in their early days when they were both molten. He calculated the amount of time it would have taken for tidal friction to give Earth its current hour day.
His value of 56 million years added additional evidence that Thomson was on the right track. Radiometric dating Overview By their chemical nature, rock minerals contain certain elements and not others; but in rocks containing radioactive isotopes, the process of radioactive decay generates exotic elements over time.
By measuring the concentration of the stable end product of the decay, coupled with knowledge of the half life and initial concentration of the decaying element, the age of the rock can be calculated. Convective mantle and radioactivity In , Thomson had been made Lord Kelvin in appreciation of his many scientific accomplishments. Kelvin calculated the age of the Earth by using thermal gradients , and he arrived at an estimate of about million years. In , John Perry produced an age-of-Earth estimate of 2 to 3 billion years using a model of a convective mantle and thin crust.
The discovery of radioactivity introduced another factor in the calculation. After Henri Becquerel 's initial discovery in , Marie and Pierre Curie discovered the radioactive elements polonium and radium in ; and in , Pierre Curie and Albert Laborde announced that radium produces enough heat to melt its own weight in ice in less than an hour. Geologists quickly realized that this upset the assumptions underlying most calculations of the age of Earth. These had assumed that the original heat of the Earth and Sun had dissipated steadily into space, but radioactive decay meant that this heat had been continually replenished.
George Darwin and John Joly were the first to point this out, in Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. October Radioactivity, which had overthrown the old calculations, yielded a bonus by providing a basis for new calculations, in the form of radiometric dating.
Ernest Rutherford in Ernest Rutherford and Frederick Soddy jointly had continued their work on radioactive materials and concluded that radioactivity was due to a spontaneous transmutation of atomic elements. In radioactive decay, an element breaks down into another, lighter element, releasing alpha, beta, or gamma radiation in the process.
They also determined that a particular isotope of a radioactive element decays into another element at a distinctive rate. This rate is given in terms of a " half-life ", or the amount of time it takes half of a mass of that radioactive material to break down into its "decay product". Some radioactive materials have short half-lives; some have long half-lives. Uranium and thorium have long half-lives, and so persist in Earth's crust, but radioactive elements with short half-lives have generally disappeared.
This suggested that it might be possible to measure the age of Earth by determining the relative proportions of radioactive materials in geological samples.
In reality, radioactive elements do not always decay into nonradioactive "stable" elements directly, instead, decaying into other radioactive elements that have their own half-lives and so on, until they reach a stable element. Such "decay series", such as the uranium-radium and thorium series, were known within a few years of the discovery of radioactivity and provided a basis for constructing techniques of radiometric dating. The pioneers of radioactivity were chemist Bertram B.
Boltwood and the energetic Rutherford. Boltwood had conducted studies of radioactive materials as a consultant, and when Rutherford lectured at Yale in ,  Boltwood was inspired to describe the relationships between elements in various decay series.
Late in , Rutherford took the first step toward radiometric dating by suggesting that the alpha particles released by radioactive decay could be trapped in a rocky material as helium atoms. At the time, Rutherford was only guessing at the relationship between alpha particles and helium atoms, but he would prove the connection four years later.
Soddy and Sir William Ramsay had just determined the rate at which radium produces alpha particles, and Rutherford proposed that he could determine the age of a rock sample by measuring its concentration of helium. He dated a rock in his possession to an age of 40 million years by this technique.
Rutherford wrote, I came into the room, which was half dark, and presently spotted Lord Kelvin in the audience and realized that I was in trouble at the last part of my speech dealing with the age of the Earth, where my views conflicted with his. To my relief, Kelvin fell fast asleep, but as I came to the important point, I saw the old bird sit up, open an eye, and cock a baleful glance at me! Then a sudden inspiration came, and I said, "Lord Kelvin had limited the age of the Earth, provided no new source was discovered.
That prophetic utterance refers to what we are now considering tonight, radium! Rutherford's scheme was inaccurate, but it was a useful first step. Boltwood focused on the end products of decay series.
In , he suggested that lead was the final stable product of the decay of radium. It was already known that radium was an intermediate product of the decay of uranium. Rutherford joined in, outlining a decay process in which radium emitted five alpha particles through various intermediate products to end up with lead, and speculated that the radium-lead decay chain could be used to date rock samples.
Boltwood did the legwork, and by the end of had provided dates for 26 separate rock samples, ranging from 92 to million years. He did not publish these results, which was fortunate because they were flawed by measurement errors and poor estimates of the half-life of radium.
Boltwood refined his work and finally published the results in His studies were flawed by the fact that the decay series of thorium was not understood, which led to incorrect results for samples that contained both uranium and thorium.
However, his calculations were far more accurate than any that had been performed to that time. Refinements in the technique would later give ages for Boltwood's 26 samples of million to 2. Rutherford remained mildly curious about the issue of the age of Earth but did little work on it.
Robert Strutt tinkered with Rutherford's helium method until and then ceased. However, Strutt's student Arthur Holmes became interested in radiometric dating and continued to work on it after everyone else had given up. Holmes focused on lead dating, because he regarded the helium method as unpromising.
He performed measurements on rock samples and concluded in that the oldest a sample from Ceylon was about 1. For example, he assumed that the samples had contained only uranium and no lead when they were formed. More important research was published in It showed that elements generally exist in multiple variants with different masses, or " isotopes ".
In the s, isotopes would be shown to have nuclei with differing numbers of the neutral particles known as " neutrons ". In that same year, other research was published establishing the rules for radioactive decay, allowing more precise identification of decay series.
Many geologists felt these new discoveries made radiometric dating so complicated as to be worthless. His work was generally ignored until the s, though in Joseph Barrell , a professor of geology at Yale, redrew geological history as it was understood at the time to conform to Holmes's findings in radiometric dating. Barrell's research determined that the layers of strata had not all been laid down at the same rate, and so current rates of geological change could not be used to provide accurate timelines of the history of Earth.
Holmes published The Age of the Earth, an Introduction to Geological Ideas in in which he presented a range of 1. No great push to embrace radiometric dating followed, however, and the die-hards in the geological community stubbornly resisted. They had never cared for attempts by physicists to intrude in their domain, and had successfully ignored them so far. Holmes, being one of the few people on Earth who was trained in radiometric dating techniques, was a committee member, and in fact wrote most of the final report.
Questions of bias were deflected by the great and exacting detail of the report. It described the methods used, the care with which measurements were made, and their error bars and limitations. Techniques for radioactive dating have been tested and fine-tuned on an ongoing basis since the s. Forty or so different dating techniques have been utilized to date, working on a wide variety of materials. Dates for the same sample using these different techniques are in very close agreement on the age of the material.
The quoted age of Earth is derived, in part, from the Canyon Diablo meteorite for several important reasons and is built upon a modern understanding of cosmochemistry built up over decades of research. Most geological samples from Earth are unable to give a direct date of the formation of Earth from the solar nebula because Earth has undergone differentiation into the core, mantle, and crust, and this has then undergone a long history of mixing and unmixing of these sample reservoirs by plate tectonics , weathering and hydrothermal circulation.
All of these processes may adversely affect isotopic dating mechanisms because the sample cannot always be assumed to have remained as a closed system, by which it is meant that either the parent or daughter nuclide a species of atom characterised by the number of neutrons and protons an atom contains or an intermediate daughter nuclide may have been partially removed from the sample, which will skew the resulting isotopic date.
To mitigate this effect it is usual to date several minerals in the same sample, to provide an isochron. Alternatively, more than one dating system may be used on a sample to check the date. Some meteorites are furthermore considered to represent the primitive material from which the accreting solar disk was formed.
Nevertheless, ancient Archaean lead ores of galena have been used to date the formation of Earth as these represent the earliest formed lead-only minerals on the planet and record the earliest homogeneous lead-lead isotope systems on the planet. These have returned age dates of 4. Severin ordinary chondrite 1.